Half-Sandwich Titanium Complexes Stabilized by a Novel Silsesquioxane Ligand: Soluble Model Systems for Silica-Grafted Olefin Polymerization Catalysts
Organometallics1998Vol. 17(24), pp. 5222–5224
Citations Over TimeTop 10% of 1998 papers
Robbert Duchateau, Hendrikus C. L. Abbenhuis, Rutger A. van Santen, Sven K.‐H. Thiele, Maurits F. H. van Tol
Abstract
The cuboctameric silsesquioxane silanol (c-C5H9)7Si8O12(OH) has been applied as a model support for silica-grafted olefin polymerization catalysts. Complexes of the type Cp‘‘[(c-C5H9)7Si8O13]TiX2 (Cp‘‘ = 1,3-C5H3(SiMe3)2; X = Cl, CH2Ph) form active α-olefin polymerization catalysts.
Related Papers
- → Half-Sandwich Titanium Complexes Stabilized by a Novel Silsesquioxane Ligand: Soluble Model Systems for Silica-Grafted Olefin Polymerization Catalysts(1998)108 cited
- → The effect of bulky substituents on the olefin polymerisation behaviour of nickel catalysts bearing [P,O] chelate ligands(2001)58 cited
- → Synthesis of Novel Dinuclear Complexes by Olefin Metathesis and Their Use in Olefin Polymerization(2011)4 cited
- → Study of the Activity and Stereoselectivity of Some Metathesis Catalysts with Acyclic Internal Olefins(2002)2 cited
- Advances in Polyhedral Oligomeric Silsesquioxane and Its Application in Polymer(2008)