‘Double asymmetric induction’ as a novel tool for high stereocontrol in Baylis–Hillman reaction
Chemical Communications2004Iss. 22, pp. 2580–2581
Citations Over TimeTop 19% of 2004 papers
Abstract
The strategy of double asymmetric induction was utilized in Baylis-Hillman reaction for the first time by the coupling of chiral aldehydes with chiral acrylate (1,2:5,6-di-O-isopropylidene-alpha-D-glucofuranose-3-acrylate) to obtain corresponding adducts with high syn diastereoselectivities (de >90%) in moderate to good yields.
Related Papers
- → Lewis base effects in the Baylis–Hillman reaction of imines with cyclohex-2-en-1-one and cyclopent-2-en-1-one(2001)67 cited
- → Synthesis of 2-amino-2,3-dihydrobenzofurans and fully substituted furans from modified Baylis–Hillman adducts(2006)29 cited
- → Synthesis of 3,5,6-trisubstituted α-pyrones from Baylis–Hillman adducts(2006)28 cited
- → ‘Double asymmetric induction’ as a novel tool for high stereocontrol in Baylis–Hillman reaction(2004)18 cited
- → Asymmetric Baylis-Hillman Reactions of Novel Bornyl Acrylate Esters(1999)14 cited