The first X-ray crystal structure determination of a dinuclear complex trapped in the [low spin–high spin] state: [FeII2(PMAT)2](BF4)4·DMF
Chemical Communications2005Iss. 8, pp. 987–989
Citations Over TimeTop 10% of 2005 papers
Abstract
The two metal centres in the doubly 1,2,4-triazole-bridged spin crossover complex [Fe(II)2(PMAT)2](BF4)4.DMF (1.DMF) are trapped in different spin states below ca. 200 K, with no evidence that this particular [LS-HS] species can be converted into the [LS-LS] form at ambient pressure.
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