Surface morphology-induced spin-crossover-inactive high-spin state in a coordination framework
Chemical Communications2021Vol. 57(12), pp. 1462–1465
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Shun Sakaida, Kazuya Otsubo, Ken‐ichi Otake, Shogo Kawaguchi, Mitsuhiko Maesato, Susumu Kitagawa, Hiroshi Kitagawa
Abstract
Here we report a surface morphology-induced spin state control in ultrathin films of a spin-crossover (SCO) material. The surface microstructure of film domains exhibited selectivity, to stabilize the SCO-active high-spin (HS) or SCO-inactive high-spin (HS2) states. To date, the latter has only been confirmed in the bulk counterpart at gigapascal pressure.
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