Thermal epimerization of diastereomeric Grignard reagents
Organic & Biomolecular Chemistry2008Vol. 7(1), pp. 41–42
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Abstract
Thermal epimerization is the key to changing the endo-to-exo ratio of the diastereomeric bornyl and fenchyl Grignard reagents from 67:33 to 96:4 and from 20:80 to 80:20, respectively.
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