Chiral metal–organic frameworks with tunable open channels as single-site asymmetric cyclopropanation catalysts
Chemical Communications2012Vol. 48(52), pp. 6508–6508
Citations Over TimeTop 11% of 2012 papers
Abstract
A pair of interpenetrated and non-interpenetrated chiral metal-organic frameworks with the same catalytic sites but different open channel sizes catalysed asymmetric cyclopropanation of substituted terminal alkenes with excellent diastereoselectivities (up to 9.6) and enantioselectivities (up to >99%).
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