Slow magnetic relaxation in carbonato-bridged dinuclear lanthanide(iii) complexes with 2,3-quinoxalinediolate ligands
Chemical Communications2012Vol. 48(62), pp. 7726–7726
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Julia Vallejo, Joan Cano, Isabel Castro, Miguel Julve, Francesc Lloret, Óscar Fabelo, Laura Cañadillas‐Delgado, Emilio Pardo
Abstract
The coordination chemistry of the 2,3-quinoxalinediolate ligand with different lanthanide(III) ions in basic media in air affords a new family of carbonato-bridged M(2)(III) compounds (M = Pr, Gd and Dy), the Dy(2)(III) analogue exhibiting slow magnetic relaxation behaviour typical of single-molecule magnets.
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