Easy access to enamides: a mild nickel-catalysed alkene isomerization of allylamides
Chemical Communications2013Vol. 49(72), pp. 7923–7923
Citations Over TimeTop 14% of 2013 papers
Abstract
The first Ni-catalysed alkene isomerization of allylamides for the synthesis of enamides was demonstrated. Various substituted N-allylamides were found to be suitable substrates for this isomerization. Isotopic labelling experiments showed that it is an intramolecular hydrogen transfer process.
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