Atomic-scale insight into the formation, mobility and reaction of Ullmann coupling intermediates
Chemical Communications2013Vol. 50(8), pp. 1006–1008
Citations Over TimeTop 10% of 2013 papers
Abstract
The Ullmann reaction of bromobenzene, the simplest coupling reagent, to form biphenyl on a Cu surface proceeds via a highly mobile organometallic intermediate in which two phenyl groups extract and bind a single surface Cu atom.
Related Papers
- → Atomic-scale insight into the formation, mobility and reaction of Ullmann coupling intermediates(2013)54 cited
- → Synthesis of Polyfunctionalized Biphenyls as Intermediates for a New Class of Liquid Crystals(2003)29 cited
- → Aspects of the metallic halide catalysed reaction of Grignard reagents with organic halides. Part V. Application to dibromobenzenes(1969)5 cited
- → Metal Vapor Reactivity of Copper Toward Substituted Bromobenzenes. Comparison with the Classical Ullmann Coupling Reaction(1989)
- Synthesis of 4′-ethyl-2,3-difluoro-1,1′-biphenyl by Suzuki coupling reaction(2013)