Enantioselective sulfoxidation reaction catalyzed by a G-quadruplex DNA metalloenzyme
Chemical Communications2016Vol. 52(62), pp. 9644–9647
Citations Over TimeTop 10% of 2016 papers
Abstract
Enantioselective sulfoxidation reaction is achieved for the first time by a DNA metalloenzyme assembled with the human telomeric G-quadruplex DNA and Cu(ii)-4,4'-bimethyl-2,2'-bipyridine complex, and the mixed G-quadruplex architectures are responsible for the catalytic enantioselectivity and activity.
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