Flash Vacuum Pyrolytic Generation of Arynes – in Retrospect
Australian Journal of Chemistry2010Vol. 63(7), pp. 1002–1006
Citations Over Time
Abstract
The development of the chemistry of benzyne and of arynes under flash vacuum pyrolytic conditions was strongly influenced by a parallel study of the chemistry of propadienones, and by the discovery of the acetylene/methylenecarbene rearrangement. A limited range of typical aryne reactions studied at The Australian National University and at Monash University from 1965 to 1996 is described, and pathways of aryne formation are considered.
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