Ruthenium-catalyzed Formation of Tertiary Amines from Nitriles and Alcohols
Chemistry Letters2011Vol. 40(5), pp. 489–491
Citations Over TimeTop 23% of 2011 papers
Abstract
Abstract A ruthenium-catalyzed tertiary-amine formation was developed using the borrowing hydrogen strategy. Various tertiary amines were obtained efficiently from nitriles and primary alcohols. Two possible pathways were found for the tertiary-amine formation under RuCl3/dppf catalytic conditions. The nitriles mainly act as a nitrogen source in this kind of transformation.
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