Strained Silacycles in Organic Synthesis: A New Reagent for the Enantioselective Allylation of Aldehydes
Journal of the American Chemical Society2002Vol. 124(27), pp. 7920–7921
Citations Over TimeTop 10% of 2002 papers
Abstract
A new reagent for the enantioselective allylation of aliphatic aldehydes has been developed. The reagent is easily prepared in a single step from commercially available materials and may be stored without significant decomposition. The reactivity of the reagent is attributed to strain-release Lewis acidity.
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