Synthesis of Side Chain Truncated 3‘ ‘-Aldehyde, 3‘ ‘-Carboxylic Acid, and 1‘ ‘-Aldehyde from Nodulisporic Acid A
Organic Letters2002Vol. 4(8), pp. 1291–1294
Citations Over TimeTop 22% of 2002 papers
Prasun K. Chakravarty, Sriram Tyagarajan, Thomas L. Shih, Steve Salva, Christine Snedden, Matthew J. Wyvratt, Michael H. Fisher, Peter T. Meinke
Abstract
An efficient synthesis of the truncated 3"-aldehyde (3) from nodulisporic acid A (1) under mild conditions is described. Further oxidation of 3 to 3"-carboxylic acid (4) and its subsequent oxidative degradation produced 1"-aldehyde (5). These new derivatives are versatile intermediates for the preparation of new, side chain modified derivatives of nodulisporic acid A. [reaction: see text]
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