Improving Foldamer Synthesis through Protecting Group Induced Unfolding of Aromatic Oligoamides
Organic Letters2006Vol. 8(22), pp. 5117–5120
Citations Over TimeTop 21% of 2006 papers
Abstract
The hydrogen bond rigidified backbones of aromatic oligoamides are temporarily interrupted by replacing the amide hydrogens with the acid-labile 2,4-dimethoxybenzyl (DMB) group, which allows the efficient preparation of long folding oligomers that, upon removal of the DMB groups, fold into multiturn helices. [structure: see text]
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